5-Fluoro-1-(3-metylbutanoyl)pyrimidine-2,4(1H,3H)-dione

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5-Fluoro-1-(3-metylbutano­yl)pyrimidine-2,4(1H,3H)-dione

The 3-methyl-butanoyl group and the 5-fluoro-uracil unit of the title compound, C(9)H(11)FN(2)O(3), are essentially coplanar, with the carbonyl group oriented towards the ring CH group and away from the nearer ring carbonyl group. The 3-methyl-butanoyl (C=)C-N-C=O torsion angle of 9.6 (2)° is comparable to that in structurally related compounds. In the solid state, two inversion-related mol-ecu...

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5-Fluoro-1-(4-meth­oxy­benz­yl)indoline-2,3-dione

In the title compound, C(16)H(12)FNO(3), the dihedral angle between the benzene ring and the plane of the indole ring system is 71.60 (6)°. In the crystal, mol-ecules stack along the b axis through π-π inter-actions between the adjacent indole-2,3-dione units with a centroid-centroid distance of 3.649 (3) Å. Inter-molecular C-H⋯O=C and C-H⋯π inter-actions further stabilize the structure, formin...

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5-Fluoro-1-(penta­noyl)pyrimidine-2,4(1H,3H)-dione

The penta-noyl group and the 5-fluoro-uracil moiety of the title compound, C(9)H(11)FN(2)O(3), are essentially coplanar, with the penta-noyl carbonyl group oriented towards the ring CH group and away from the nearer ring carbonyl group. In the crystal structure, two inversion-related mol-ecules form a dimer structure, in which two N-H⋯O hydrogen bonds generate an inter-molecular R(2) (2)(8) rin...

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1-(3-Chloro­benz­yl)-5-iodo­indoline-2,3-dione

In the title compound, C(15)H(9)ClINO(2), which possesses anticonvulsant activity, the iodo-indoline ring system is essentially planar (maximum deviation 1.245 Å) and is oriented with respect to the 3-chloro-benzyl ring at a dihedral angle of 76.59 (3)°. In the crystal, there is a π-π contact between iodo-indoline ring systems [centroid-centroid distance = 3.8188 (4) Å].

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5′′-(4-Chloro­benzyl­idene)-4′-(4-chloro­phen­yl)-5-fluoro-1′,1′′-dimethyl­indoline-3-spiro-2′-pyrrolidine-3′-spiro-3′′-piperidine-2,4′′-dione

The piperidine ring of the title compound, C(30)H(26)Cl(2)FN(3)O(2), adopts a twisted chair conformation. The pyrrolidine ring has a twisted envelope structure with the N atom at the flap [displaced by 0.592 (3) Å]. The fluoro-oxindole, chloro-phenyl and chloro-benzyl-idene groups are planar with r.m.s. deviations of 0.0348, 0.0048 and 0.0048 Å, respectively. The structure is stabilized by inte...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808006296